Le ZnO de type P en tant que matériau multifonctionnel pour les dispositifs optoélectroniques
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Le ZnO est l'un des mat�riaux les plus importants parmi les oxydes conducteurs transparents (TCO). Le ZnO constitue une classe de mat�riaux importante sur le plan technologique, pr�sentant des caract�ristiques d'att�nuation des UV exceptionnelles, bloquant 95 % de l'ensemble du rayonnement UV. �tant donn� que la bande interdite du ZnO se situe bien au-dessus du spectre visible, les films pr�par�s sont �lectriquement conducteurs, ce qui conduit � des applications pour des dispositifs � jonction p-n transparents. Le ZnO pr�sente naturellement une conductivit� de type n en raison d'un grand nombre de d�fauts natifs, tels que des lacunes d'oxyg�ne et des interstitiels de zinc, ce qui rend difficile l'obtention de films minces de ZnO de type p. La difficult� � former un mat�riau ZnO de type p est due � son effet d'auto-compensation, � son niveau d'accepteur profond et � la faible solubilit� des dopants accepteurs. En g�n�ral, la r�alisation d'une conductivit� de type p dans un film mince de ZnO peut �tre rendue possible en substituant des �l�ments du groupe I (Li, Na, K et Ag) aux sites de Zn, ou des �l�ments du groupe V (N, P, As, Sb) aux sites de O, ou encore en substituant simultan�ment des �l�ments des groupes III et V respectivement aux sites de Zn et de O.
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