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The Encyclopedia of Chemical Electrode Potentials by Marvin Antelman

The Encyclopedia of Chemical Electrode Potentials

by Marvin Antelman
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Book cover type: Paperback
  • ISBN13: 9781461333760
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Springer
  • Publisher Imprint: Springer
  • Publication Date:
  • Pages: 288
  • Original Price: EUR 49.99
  • Language: English
  • Edition: Softcover Repri
  • Item Weight: 467 grams
  • BISAC Subject(s): General and Chemistry / Physical & Theoretical

This book is an attempt to compile the most comprehensive listing of chemical electrode potentials to date. In compiling this encyclopedia, many papers, articles, and publi- cations-often with contradictory data-were consulted. Of all the par- published material available, the authors found the following of ticular interest: G. Milazzo and S. Caroli, Tables of Standard Electrode Poten- tials, John Wiley and Sons, Inc. (1978). A. J. deBethune and N. A. Swendeman Loud, Standard Aque- ous Electrode Potentials and Temperature Coefficients at 25 C, Clifford A. Hempel (1964). W. Mansfield Clark, Oxidation-Reduction Potentials of - ganic Systems, The Williams and Wilkins Co. (1960). However, it was our intent also to include unpublished complex forma- tion EMF data. Furthermore, when we consulted published EMF data, we found that the compilations often paid no attention to disparate conditions and varying pressures and electrolyte concentrations. To achieve a useful compilation, we resorted to Nernst equation thermodynamic calculations to reconcile disparate data. We also uti- lized the following relationships to calculate EMF values for inclusion in our tables from association constants: In K = nFE log K = -nE(16. 9) RT As a practical example, consider the reaction 3 Ca + Nta- - 2e = Ca(Ntar We may write 2 Ca - 2e = Ca+ EO = -2. 87 2 3 Ca+ + Nta- = Ca(Ntar E, = ? 3 Ca - 2e + Nta- = Ca(Ntar E2 = ? xl xII INTRODUCTION Given log K Ca(Ntaf = 6. 41, 6. 41 = -(2)(16.

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