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Elektrische Überführung Und Strukturuntersuchungen in Salzschmelzen by Joachim Richter

Elektrische Überführung Und Strukturuntersuchungen in Salzschmelzen

by Joachim Richter
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Book cover type: Paperback
  • ISBN13: 9783531028811
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Vs Verlag Fur Sozialwissenschaften
  • Publisher Imprint: Vs Verlag Fur Sozialwissenschaften
  • Publication Date:
  • Pages: 166
  • Original Price: USD 59.99
  • Language: German
  • Edition: 1979
  • Item Weight: 250 grams
  • BISAC Subject(s): General

FUr die physikalisch-chemischen Ph omene, die an Salzschmel- zen beobachtet werden, g1bt es zur Zeit noch keine umfassende theoret1sche Darstellung.Daher 1st es von gro3em Interesse, Uber mBgl1chst viele Typen von Salzschmelzen Me3daten zu sam- meln. Besonders hervorzuheben sind Daten Uber Transportvorg e in der Schmelze. Im Rahmen des vorliegenden Forschungsvorhabens werden die UberfUhrungszahlen der Alkal1n1trat-Sllbern1trat-Schmelzen der Form MN0 + AgN0 mit M = L1, Na, K, Rb, Cs in Abh ig- 3 3 keit von der Zusammensetzung und der Temperatur best1mmt. Da- rUber hinaus sollt bei einem ein-zweiwert1gen System - der hochviskosen Schmelze Ca (N0 )2 + AgN0 - die UberfUhrungs- 3 3 zahlen in Abh 1gke1t yom Molenbruch bei 573,15 K bestimmt werden. Be1 der D1skussion der elektr1schen Transportvorg ge nehmen die UberfUhrungszahlen be1 F1Uss1gkeiten mit Ionenleitungs- mechanismus einen wichtigen Platz ein. Aus ihnen lassen sich zusammen mit anderen Transportdaten die Reibungskoeffizienten, die ein Ma3 fUr die Wechselwirkungskrafte zwischen den ioni- schen Bestandteilen der Ionenschmelze sind, berechnen (18, 21, 22). Zur Ermittlung der Transportdaten, die nicht-isotherme Salzschmelzen charakterisieren, werden UberfUhrungszahlen eben- falls dringend benBtigt (8, 20, 23). Alle diese grundlegenden Daten tragen dazu bei, anwendungstechnische Probleme der Schmel- zen, die Optimierung fUr ihren Einsatz und Korrosionsprobleme zu lBsen.

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