Thermochemische Untersuchungen Im System Sio2 Und Na2o -- Sio2
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Über die Thermochemie der Silikate liegen bereits zahlreiche Arbeiten vor. Die Ergebnisse reichen aber in vielen Fällen noch nicht aus, um die energetischen Verhältnisse innerhalb von Ein- und Mehrstoffsystemen lückenlos und widerspruchsfrei darstellen zu können. Das liegt zu einem Teil daran, da manche Autoren sich nur eng gefa te Themen stellen und auf die Verfolgung weiterführender Zusammenhänge verzichten. Zu ande- ren ist es aber oft grundsätzlich schwierig, die einzelnen speziellen Me ergebnisse verschiedener Laboratorien zu einem sinnvollen Ganzen zu kombinieren, da mehrere Einflu faktoren, die wir auch i Laufe dieser Arbeit durchdiskutieren müssen, die Me ergebnisse je nach der verwende- ten Arbeitsmethode von Fall zu Fall verschieden beeinflussen können. Die Zustandsschaubilder geben i.a. umfassende und lückenlose Auskunft über alle Gleichgewichtsverhältnisse, die bei den verschiedenen Zusam- mensetzungen, Temperaturen und Drucken eintreten können. Das Ziel syste- matischer Forschung mu sein, in ähnlich erschöpfender Weise alle übri- gen Phänomene und Eigenschaften der Körper in Abhängigkeit von den ge- nannten Parametern darzustellen. So ist es z.B. Aufgabe der Thermochemie, die experimentell ermittelten Grundlagen bereitzustellen für die zuverlässige Berechnung aller statt- findenden Wärmetönungen, wenn Zusammensetzung, Druck und Temperatur inner- halb eines Systemes in beliebiger Weise verändert werden. Ther ochemi- sehe Untersuchungen können aber auch für die Diskussion andersgearteter Probleme fruchtbar werden, die z.B. bei Betrachtung von Stabilitätsver- hältnis, Struktur, Bindungsenergie und Bindungstypus auftreten. Auch über die Existenz von Verbindungen können in manchen Fällen Aussagen gemacht werden.
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