Über Ein Ozon -- Registriergerät Und Untersuchung Der Zeitlichen Und Räumlichen Variationen Des Troposphärischen Ozons Auf Der Nordhalbkugel Der Erde
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In der vorliegenden Arbeit wird im ersten Teil ein Gerät beschrieben, mit dem eine automati- sche Dauerregistrierung bodennahen Ozons ermöglicht wird. Das bekannte Depolarisationsverfahren wurde in der Arbeit derart modifiziert, da die Anode und die Kathode räumlich getrennt sind und da das anodisch gebildete Jod durch einen kontinuierlichen Zu- flu an KJ -Lösung ständig entfernt wird. Der Oxydationsproze , d. h. die Reaktion zwischen der ozonhaltigen Luft und der 2 %-igen KJ -Lö- sung, und der Me proze wurden damit zu einem kontinuierlichen Verfahren vereint. Es wird dabei ein Strom registriert, welcher unmittelbar in einem festen Verhältnis zu der pro Sekunde mit der Luft zu- geführten Ozonmenge steht. Die Eichung des Gerätes nach zwei verschiedenen und unabhängigen Verfahren bestätigt die theo- retisch erwarteten Werte. Mehrmonatige Dauerregistrierungen an 6 verschiedenen in- und ausländischen Observatorien stel- len die Tauglichkeit des Gerätes unter Beweis. Die bei diesen Registrierungen erzielten Me ergebnisse werden diskutiert. Das besondere Interesse der Untersuchung gilt dabei den Tagesmaxima des bodennahen Ozons und ihrer Eignung als Ma für den zeitlich veränderlichen Ozongehalt der freien Troposphäre. Eine Korrelationsrechnung zwischen den Tagesmaxima des bodennahen Ozons und den zugehörigen mittleren Werten des Ozons der freien Troposphäre zeigt für einen festen Ort, da das Tagesmaximum des bodennahen Ozons im statistischen Mittel den Durchschnittswert des troposphärischen Ozons gut repräsentiert. Im zweiten Teil der Arbeit werden mit Hilfe der Me ergebnisse von ca. 2500 Ozon-Radiosondenauf- stiegen über Nordamerika und Europa zeitliche und gro räumige Variationen des mittleren troposphä- rischen Ozongehaltes in der Nordhemisphäre untersucht.
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