Kohlungsgleichgewichte in Festen Mehrstoffsystemen Mit Eisen, Nickel Und Chrom Sowie Ihre Thermodynamische Auswertung
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Eine vergleichende Gegenuberstellung der gemessenen und berechneten Kohlenstoffaktivitat der festen, reinen Eisen-Kohlenstoff-Legierung ist nach einer erneuten, thermodynamisch begrundeten Auswertung bis hin zum UberschuBanteil der Entropie die Auswertungsbasis fUr die Bestimmung der partiellen energetischen GraBen des Kohlenstoffs. Vorhandene Unterschiede im Experiment besonders aber in der sich anschlieBenden Auswertungsm ethode zum angelsachsischen Schrifttum wurden aufgezeigt. Die in der eigenen Auswertung anfallenden energetischen GraBen des Kohlenstoffs werden als konzentrationsabhangig, aber temperatur - abhangig erkannt. - 24 - Literaturangaben 1. J. K. Rao und B. P. Jalan: Metallg. Trans. 1972 vol. 3 S. 2465/77 2. She Ban"ya, J. F. Elliott und J. Chipman: Trans. TMS - AIME 1969 vol. 245 S. 1199/1206 3. . L. S. Darken und R. P. Smith: J. Am. Chern. Soc. 1946 vol. 68 S. 1172/75 4. R. H. Fowler und E. A. Guggenheim: Statistical Thermodynamics, The Mc. Millan Co. New York 1939 5. J. Chipman und E. F. Brush: Trans. TMS -AIME 1968 vol. 242 S. 35/41 6. L. S. Darken: Trans. TMS - AIME 1967 vol. 239 S. 80/89 7. S. Tackeuchl und S. Kachi: Sci. Rept. Res. Inst. TohokuUniv. Serie A 1950 vol. 2 S. 691/718 8. D. R. Poirier: Trans TMS AIME 1968 vol. 2 S. 685/90 9. L. Kaufman, S. V. Radcliffe und M. Cohen: AIME Symposium on Decomposition of Austenit/V. Zackay Ed. 1962 S. 313/52 10. R. Speiser und J. W. Spretnak: Trans. ASM 1955 vol. 47 S. 493/507 11. E. ScheH: Archlv Eisenhtitt. 1960 vol. 22 S. 37/52 12. M. Temkin und L.
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