Organische Leiter, Halbleiter Und Photoleiter
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Organische Stoffe bilden in Form der Hochpolymere mit einer Jahresproduktion von 40 Mio. t einen wesent- lichen Teil der Werkstoffe der modernen Technik. Etwa ein Drittel dieser Menge, das heiJ3t rund 13 Mio. t, werden als Isolierstoffe jahrlich von der Elektrotechnik und Elektronik verarbeitet. Demgegeniiber tritt die Anwen- dung elektronisch leitender organischer Substanzen umfangma13ig noch weit zuriick, wenn sie auch in der Elektrophotographie nach Selen bereits an zweiter Stelle stehen. Beriicksichtigt man, daB organische Halbleiter und Leiter 1960 noch als Kuriositat galten, ist der rasche Wandel ihrer technischen Bedeutung jedoch offensicht- lich. Seit 1960 hat sich der Forschungsschwerpunkt zunachst auf halbleitende und photoleitende organische Stoffe und spater mit auBerordentlicher Intensitat auf die hochleitfahigen organischen Stoffe verlagert. Diese Ent- wicklung wird von praktischen Zielen get ragen, die in Bezeichnungen wie "organische Metalle", "organische Legierungen" und "organische Supraleiter" offen ausge- sprochen werden. Ohne Zweifel nimmt die Suche nach organischen Supraleitern nicht nur wissenschaftsjournalistisch, son- dern inzwischen ebenso del' technischen Problemstellung nach die Spitzenposition ein. Es geht dabei auch um die Klarung der experimentellen Realisierbarkeit der Exzito- nen-Supraleitung, die mit den eindimensionalen Struk- turen in engem Zusammenhang steht und von der Sprung- temperaturen bis zu Zimmertemperatur erhofft werden.
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