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Activating Unreactive Substrates: The Role of Secondary Interactions by Carsten Bolm, F. Ekkehardt Hahn

Activating Unreactive Substrates: The Role of Secondary Interactions

by Carsten Bolm , F. Ekkehardt Hahn
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Book cover type: Hardcover
  • ISBN13: 9783527318230
  • Binding: Hardcover
  • Subject: Chemistry
  • Publisher: Wiley
  • Publisher Imprint: Wiley-VCH
  • Publication Date:
  • Pages: 481
  • Original Price: USD 281.75
  • Language: English
  • Edition: N/A
  • Item Weight: 1044 grams
  • BISAC Subject(s): Chemistry / Organic

From the Back Cover
Current knowledge about the reaction mechanisms of various metalloenzymes and catalysts demonstrates that substrate conversions occurring at the metal center are controlled by secondary interactions. Such secondary interactions comprise all properties within the ligands of a coordination compound -- yet outside of the first coordination sphere -- which influence the reaction profile at the metal center. Direct utilization of the variable "secondary interactions" allows the electronic structure, geometry and reactivity of coordination compounds to be controlled, allowing a catalytic activation and functionalization of natural and unreactive bulk gases of the atmosphere and simple hydrocarbons.
This first comprehensive treatment of this important approach in catalysis research covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community.
A must for chemists.

Carsten Bolm became Professor of Organic Chemistry at the University of Marburg (Germany) in 1993, and since 1996 he has been full professor for Organic Chemistry at the RWTH Aachen University (Germany). He held visiting professorships at universities in Madison, Wisconsin (USA), Paris (France), Florence (Italy), Milan (Italy), Namur (Belgium) and Tokyo (Japan). His list of awards include the Heinz-Maier-Leibnitz prize, the ADUC-Jahrespreis for habilitands, the annual prize for Chemistry of the Akademie der Wissenschaften zu Göttingen, the Otto-Klung prize, the Otto-Bayer award, a fellowship of the Japan Society for the Promotion of Science, and the Prix Franco-Allemand. With Wiley-VCH he edited books (together with Matthias Beller) on Transition Metals for Organic Chemistry and (together with Takeshi Toru) on Organosulfur Chemistry in Asymmetric Synthesis.

Ekkehardt Hahn became Professor of Inorganic Chemistry at the Free University of Berlin in 1992. Since 1998 he is full professor of Inorganic Chemistry at the University of Münster (Germany). He held visiting professorships at the University of California, Berkeley (USA), the Universidad de Zaragoza (Spain), the National University of Singapore, and the Institute of Organic Chemistry of the Academia Sinica, Shanghai (PR China). His lists of awards includce a Karl Winnacker Fellowship and the election to the Academia de Ciencas Exactas, Fisicas, Quimicas y Naturales de Zaragoza, Spain. He holds a Julius von Haast visiting Professorship at the University of Auckland (New Zealand) and since 2004 serves as Permanent Secretary of the International Conference on Organometallic Chemistry

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