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Couches Polycristallines Orientées d''aragonite Biomimétique by Krauss-C

Couches Polycristallines Orientées d''aragonite Biomimétique

by Krauss-C
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Book cover type: Paperback
  • ISBN13: 9786131537462
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Omniscriptum
  • Publisher Imprint: Omniscriptum
  • Publication Date:
  • Pages: 176
  • Original Price: GBP 51.0
  • Language: French
  • Edition: N/A
  • Item Weight: 268 grams
  • BISAC Subject(s): Physics / General

On retrouve le Carbonate de Calcium dans de nombreux matériaux du Vivant. La croissance de ses différentes formes allotropiques en présence de molécules biologiques est influencée en terme d'organisation cristalline, de microstructure et d'ordre à grande échelle. La voie électrochimique a été retenue pour sa vitesse de formation de dépôt ainsi qu'un bon contrôle des paramètres instrumentaux. Nous avons sélectionné l'aragonite dans le dépôt ainsi que sa croissance texturée rappelant celle de la nacre de Haliotis tuberculata tuberculata. Une croissance en plaquettes pseudo-hexagonales orientées, présentant un double-maclage et une orientation d'environ 60 les unes par rapport aux autres, rappelle les observations faites sur les nacres de différents mollusques. Une étude par diffraction des rayons X sur des dépôts obtenus en présence de chitosan et de molécules organiques extraites de nacres naturelles montre leur influence sur la texture cristalline, les mailles de l'aragonite et les groupements carbonate. Le décalage de l'atome de carbone par rapport au plan des oxygènes de ce groupement révèle la déformation induite par les molécules durant la croissance cristalline.

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