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Dépôt Pyrochimique Du Silicium by Bieber-A

Dépôt Pyrochimique Du Silicium

by Bieber-A
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Book cover type: Paperback
  • ISBN13: 9786131531354
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Omniscriptum
  • Publisher Imprint: Omniscriptum
  • Publication Date:
  • Pages: 188
  • Original Price: GBP 57.0
  • Language: French
  • Edition: N/A
  • Item Weight: 282 grams
  • BISAC Subject(s): Chemistry / General

L'accroissement continuel de la consommation d'énergie favorise le développement des énergies renouvelables, notamment le solaire photovoltaïque. Afin de diminuer le coût du kWh photovoltaïque, l'une des alternatives pourrait ètre le retraitement électrochimique des déchets concentrés en silicium permettant d'obtenir du silicium purifié. Le sujet de ce travail de thèse est d'évaluer la faisabilité de l'électroraffinage du silicium en milieux de fluorures fondus, notamment avec l'obtention d'un dépôt de silicium exempt de sel. Un alliage Si-Fe a été utilisé comme anode pour les expériences d'électroraffinage. L'utilisation du MEB a permis de mettre en évidence une dissolution sélective du silicium à l'anode. Des dosages du bain et du dépôt de silicium, par ICP-AES, ont permis de conclure respectivement que le fer ne se dissolvait pas dans le bain et ne se déposait pas à la cathode. Des dépôts de silicium d'une pureté supérieure à 99,9% ont été obtenus par électroraffinage avec des taux de récupération de 99%.

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