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Electronic and Atomic Structure for Energy Storage Materials by Priyanka L. Yadav, Abhijeet R. Shelke, Rahul B. Patil

Electronic and Atomic Structure for Energy Storage Materials

by Priyanka L. Yadav , Abhijeet R. Shelke , Rahul B. Patil
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Book cover type: Paperback
  • ISBN13: 9786209087479
  • Binding: Paperback
  • Subject: N/A
  • Publisher: LAP Lambert Academic Publishing
  • Publisher Imprint: LAP Lambert Academic Publishing
  • Publication Date:
  • Pages: 184
  • Original Price: GBP 69.51
  • Language: English
  • Edition: N/A
  • Item Weight: 254 grams
  • BISAC Subject(s): General

Research shows that introducing eg electrons through Mn3⁺ oxidation states enhances the electrochemical properties of MnO₂ compounds. When alkali metals (Na⁺, Li⁺, K⁺) are inserted into α- and β-MnO₂ structures, they cause topotactic Mn reduction and phase competition between the two forms. This cation insertion creates charge compensation and fast ion transport channels, improving charge storage and electrochemical performance, though the mechanism is not yet fully understood. During cycling, Na⁺ and K⁺ intercalation in α-MnO₂ induces a β-MnO₂ phase and facilitates Mn⁴⁺/Mn3⁺ redox transitions. Despite promising results, issues like cyclic stability, self-discharge, and corrosion remain. X-ray absorption spectroscopy (XAS), including XANES and EXAFS, is used to study these redox and structural changes. Overall, Na and K incorporation improves MnO₂ electrode stability and performance, offering potential for advanced supercapacitor applications. This study provide indetail understanding about the materials requirements for the energy storage applications in the context of electronic and atomic structure.

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