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Elektrochemische Messungen an Eisen-Sauerstoff-Schmelzen by Wilhelm Anton Fischer

Elektrochemische Messungen an Eisen-Sauerstoff-Schmelzen

by Wilhelm Anton Fischer
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Book cover type: Paperback
  • ISBN13: 9783663062783
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Vs Verlag Fur Sozialwissenschaften
  • Publisher Imprint: Vs Verlag Fur Sozialwissenschaften
  • Publication Date:
  • Pages: 70
  • Original Price: USD 59.99
  • Language: German
  • Edition: 1967
  • Item Weight: 132 grams
  • BISAC Subject(s): General

Die Temperaturabhängigkeit der Preien Enthalpie der Reaktion (1) im Bereich von 1550 bis 1750 C wurde mit der Zelle (2) auf elektrochemischem Wege bestimmt. Die Zelle besteht aus einem gasdichten Rohr aus stabiIisiertem Zirkonoxyd, welches innen eine eingestampfte Elektrode enthält und auBen von einer aufgesinterten Schicht aus stabiIisiertem Zirkonoxyd umgeben ist. Zur Messung wird die Zelle in die Schmelze getaucht. Das Dampf- Wasserstoff-Gemisch, welches die innere Elektrode umspült, bzw. der Sauer- stoffgehalt der Eisenschmelze werden so lange verändert, bis die EMK den Wert Null annimmt. Das Gleichgewicht der Reaktion (1) ist damit erreicht. Aus den analytisch ermittelten Sauerstoffgehalten der Eisenschmelzen und den Sauerstoffpartialdrücken des Dampf-Wasserstoff-Gemisches wird für die Tempe- raturabhängigkeit der Reaktionsenthalpie der Wert L1G = - 28090 - 0,50' T (9) ermittelt. Die Sauerstoffpartialdrücke werden aus den EMK-Werten der elektrochemischen Kette (5) berechnet. Aus diesen und den zugehörigen H20 /H2-Verhältnissen ist die Temperaturabhängigkeit der Preien Enthalpie der Reaktion (11) bestimmt worden.

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