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Micelles inverses d''aot et de c12e4 by Abel-S

Micelles inverses d''aot et de c12e4

by Abel-S
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Book cover type: Paperback
  • ISBN13: 9786131533792
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Univ Europeenne
  • Publisher Imprint: Univ Europeenne
  • Publication Date:
  • Pages: 228
  • Original Price: GBP 59.0
  • Language: French
  • Edition: N/A
  • Item Weight: 341 grams
  • BISAC Subject(s): Life Sciences / Biophysics

Cette th�se a pour objectif d''�tudier � l''aide de simulations de dynamique mol�culaire, les propri�t�s structurales et volum�triques (volume et compressibilit� isotherme) des micelles inverses constitu�es d''un d�tergent ionique, l''AOT et non-ionique, le C12E4, en fonction de la quantit� d''eau solubilis�e dans les micelles (donn�e par le rapport Wo=[eau]/[d�tergent]). Nous montrons que les micelles d''AOT ont toutes une forme ellipso�dale avec un rayon qui varie lin�airement avec le rapport Wo. Dans les plus petites micelles, les propri�t�s statiques et dynamiques de l''eau confin�e sont fortement perturb�es par la forte densit� en ions et par le nombre de mol�cules d''eau li�es aux t�tes polaires. Les compressibilit�s isothermes des micelles varient lin�airement avec le rapport Wo. La forte d''hydratation des t�tes polaires favorisent la stabilit� de la structure secondaire d''un peptide encapsul� dans les micelles d''AOT. Enfin, pour les micelles de C12E4, la faible hydratation des micelles favorisent la conformation en h�lice des t�tes polaires des C12E4 et le pi�geage de l''eau confin�e au niveau des t�tes, ce qui ralentie leur diffusion de translation par rapport � l''eau pure.

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