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Pression de Vapeur: Mesure Et Modélisation by Abou-Naccoul-R

Pression de Vapeur: Mesure Et Modélisation

by Abou-Naccoul-R
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Book cover type: Paperback
  • ISBN13: 9783841633033
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Omniscriptum
  • Publisher Imprint: Omniscriptum
  • Publication Date:
  • Pages: 196
  • Original Price: GBP 56.0
  • Language: French
  • Edition: N/A
  • Item Weight: 295 grams
  • BISAC Subject(s): Chemistry / General

La pression de vapeur une donnée essentielle dans l'identité des composés organiques et inorganiques. Dans ce perspective, nous avons amélioré un appareil à saturation de gaz inerte existant au laboratoire. Une fois le bon fonctionnement de l'appareil vérifié (par mesure de la tension de vapeur d'un composé de référence: le phénanthrène) nous avons étudié des n-alcanes compris entre le C30 et le C60 ainsi que 8 hydrocarbures aromatiques polycycliques dans un large domaine de température (20 à 320 C) et de pression (10-1 Pa à 10-7 Pa). Les résultats obtenus ont été comparés avec la littérature lorsque celle-ci est disponible. La détermination des tensions de vapeur de composés inorganiques d'intérèt industriel: tétrachlorure de Zirconium (ZrCl4) et le tétrachlorure d'hafnium (HfCl4) a été également entreprise. Les résultats expérimentaux des hydrocarbures polyaromatiques nous ont permis l'amélioration d'une équation d'état cubique (dérivée de celle de Peng-Robinson) dont les paramètres sont estimés par une méthode de contribution de groupes développée par Rauzy-Coniglio. Les tensions de vapeur prédites par le modèle sont en bon accord avec les valeurs expérimentales.

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