Synthese von Nickel(II)heteroarylalkenolaten

Name: Synthese von Nickel(II)heteroarylalkenolaten
Brand: Grin Verlag
SKU: 9783668939707
Price: 3317.0 INR
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by Sadik Mejid

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ISBN13: 9783668939707
Binding: Paperback
Subject: N/A
Publisher: Grin Verlag
Publisher Imprint: Grin Verlag
Publication Date: September 6, 2019
Pages: 56
Original Price: USD 39.5
Language: German
Edition: 1. Auflage
Item Weight: 87 grams
BISAC Subject(s): Chemistry / Inorganic

About The Book

Projektarbeit aus dem Jahr 2015 im Fachbereich Chemie - Anorganische Chemie, Note: 1,3, Universität zu Köln (Institut für organische Chemie), Sprache: Deutsch, Abstract: In den letzten zwei Jahrzehnten hat es ein wachsendes Interesse an der Entwicklung der Chemie ein- oder zweikerniger Alkoxy und Alkyl-Organometallkomplexe gegeben. Dieses Interesse ergibt sich aus ihrer faszinierenden Strukturchemie, interessanter katalytischer Eigenschaften und einem hohen Potential für industrielle Anwendungen z. B. für die Abscheidung von Metalloxidschichten. Alkoxide und deren Derivate gehören zu den attraktivsten Vorstufen zur Herstellung von Oxidmaterialien. Ihre Attraktivität liegt zuallererst in der Tatsache, dass sie leicht zugänglich sind und aus kostengünstigen Verbindungen synthetisiert werden können. Darüber hinaus sind Alkoxidliganden über Wärmebehandlungen leicht entfernbar. Die Metallalkoholate M(OR)x, (M = ein Metall der Wertigkeit x; R = Alkyl oder Aryl-Gruppe) sind ausgezeichnete Vorstufen für die Abscheidung von Metalloxiden. Ihre Anwendung in der Optoelektronik, als Supraleiter und Keramiken führte zu einer Renaissance des Interesses an der Chemie dieser Verbindungen. Professor Mehrotra und seine Gruppe haben vor Jahrzehnten äu erst wichtige Fortschritte in der Synthese von Hetermetalloalkoxiden gemacht, das hei t Verbindungen, die zwei, drei oder vier verschiedene Metalle in einem Cluster-Molekül beinhalten. Im Jahr 1978 veröffentlichte Professor Bradley von der Universität London sein Buch mit dem Titel "Metal Alkoxides", auf das hier als Grundreferenzquelle verwiesen wird. Bereits 1958 stellte Bradley für homometallische Alkoxide die generelle Tendenz zur Ausbildung höherer bevorzugter Koordinationszahlen fest. Hierbei wird zumeist der geringstmögliche Polymerisationsgrad über (μ- und μ3) Alkoxo-Brücken zwischen ähnlichen Metallen ausgebildet. Die Zeitschriften "Transition Metal Alkoxides" (zu Deutsch Übergangs-metallalkoxide) von Mehrotra und Chisholm

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