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Untersuchungen Über Reaktionen in Flüssigem Ammoniak by Otto Schmitz-Dumont

Untersuchungen Über Reaktionen in Flüssigem Ammoniak

by Otto Schmitz-Dumont
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Book cover type: Paperback
  • ISBN13: 9783663032274
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Vs Verlag Fur Sozialwissenschaften
  • Publisher Imprint: Vs Verlag Fur Sozialwissenschaften
  • Publication Date:
  • Pages: 96
  • Original Price: GBP 45.99
  • Language: German
  • Edition: 1955
  • Item Weight: 259 grams
  • BISAC Subject(s): General

Fl�ssiges Ammoniak ist ein Medium, das dem Wasser in seinen Eigenschaften weitgehend analog ist. Insbesondere ist es in der Lage, wie Wasser eine gro e Anzahl von Elektrolyten zu l�sen, wobei eine Dissoziation in Ionen erfolgt. Ferner besitzt fl�ssiges Ammoniak eine Eigendissoziation ( 1 ) die der des Wassers an die Seite zu stellen ist: (2) Bedingt wird diese Eigendissoziation durch die amphiproten Eigenschaften des Ammoniaks bzw. Wassers d. h. die F�higkeit, sowohl H+ bei Gegenwart eines Protonenacceptors unter Bildung von NH bzw. OH- abzudissoziieren 2 als auch infolge Vorhandenseins eines einsamen Elektronenpaares H+ unter Bildung von NH + bzw. H 0+ zu addieren. Man erkennt durch Gegen�berstel- 4 3 lung von (1) und (2), da NH + dem H 0+ und NH - dem OH- entspricht. Im 3 2 4 "Ammonosystem" ist also NH + das s�ureanaloge Kation und NH - das basen- 2 4 analoge Anion. Hinsichtlich der Eigendissoziation besteht allerdings ein sehr gro er gradueller Unterschied, denn fl�ssiges Ammoniak ist in viel geringerem Ma e dissoziiert als Wasser. Die Ionenprodukte und -33 -14 unterscheiden sich um viele Gr� enordnungen: P = 10, P = 1-10 - NH3 H20 Demgem� ist die Ammonolyse viel geringer als die Hydrolyse, wenn ein und derselbe Stoff einmal in fl�ssigem Ammoniak das anderemal in w�ssriger L�sung betrachtet wird.

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