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Volume 25: Optical Methods of Investigating Solid Bodies by D. V. Skobel Tsyn

Volume 25: Optical Methods of Investigating Solid Bodies

by D. V. Skobel Tsyn
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Book cover type: Paperback
  • ISBN13: 9781468472080
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Springer
  • Publisher Imprint: Springer
  • Publication Date:
  • Pages: 188
  • Original Price: EUR 49.99
  • Language: English
  • Edition: N/A
  • Item Weight: 489 grams
  • BISAC Subject(s): Optics, Electrical, and Lasers & Photonics

The principal results of the work are as follows: 1. A simplified technique was devised for obtaining Raman spectra of powders. 2. The Raman and infrared absorption spectra of the following oxides were investigated: AsP3' SbP3' As 0 - SbP5. Te02. Ge02 (two forms) in the crystalline state, and ASP3' Ge02' Te0 in the glassy state. 2 5 2 3. The vibrational spectra of the crystalline and glassy forms of the oxides ASP3' Ge02' Te02 are simi- lar in many main respects, indicating a similarity of their structural units which determine the vibrational spec- tra of these substances. 4. By a study of the vibrational spectrum it was shown that arsenious anhydride has a molecular structure and consists of As0 molecules having symmetry of the point group Td' The force constants and vibration fre- 4 6 quencies of the As 0 molecule were calculated. and the vibrational spectrum of arsenious anhydride was re- 4 6 liably interpreted with the aid of these results. 5. A similar result was obtained for antimonous anhydride. consisting of Sb0 molecule.s with symmetry 4 6 ofthe point group Td. The force constants for this molecule were found and the vibrational spectrum was calculated.

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