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Elektrochemische Analytik by Günter Henze, Rolf Neeb

Elektrochemische Analytik

by Günter Henze , Rolf Neeb
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Book cover type: Paperback
  • ISBN13: 9783642701740
  • Binding: Paperback
  • Subject: N/A
  • Publisher: Springer
  • Publisher Imprint: Springer
  • Publication Date:
  • Pages: 384
  • Original Price: EUR 70.08
  • Language: German
  • Edition: Softcover Repri
  • Item Weight: 640 grams
  • BISAC Subject(s): Food Science / General

Die ersten elektrochemischen Analysenverfahren wurden in der zweiten Halfte des vergangenen J ahrhunderts entwickelt. 1864 ver6ffentlichte Gibbs die Ergebnisse seiner Untersuchungen "Ober die Anwendung der elektrolytischen Ausfallung von Kupfer und Nickel in der Analyse". DaB die Potentialdifferenz an der Phasengrenzflache zwischen Glas und LOsung vom Sauregehalt der LOsung abhangig ist, wurde bereits 1906 von Cremer beschrieben und war eine wegweisende Erkenntnis fUr die Entwicklung der Glaselektrode. Die M6glichkeit der potentiometrischen Bestimmung von Titrationsendpunkten fUhrte zu einer breiten Anwendung der MaBanalyse. Die 1921 von Miiller erschienene Monographic iiber die "Elektrometrische (potentiometrische) MaBanalyse" veran- schaulicht den damaligen Entwicklungsstand. Heyrovsky fUhrte 1922 die Polarographic ein und er6ffnete der elektrochemi- schen Analytik damit v6llig neue Wege. 1m Ergebnis der weiteren Entwicklung stehen uns heute leistungsfahige polarographische und voltammetrische Methoden fUr die Spurenanalyse zahlreicher anorganischer und organischer Substanzen zur Ver- fUgung. Fiir die DurchfUhrung elektrochemischer Bestimmungen sind die apparativen Aufwendungen im allgemeinen geringer als fUr verschiedene andere Analysenverfah- reno Hinzu kommt, daB mit der Entwicklung der Elektronik auch die MeBtechnik verfeinert und teilweise automatisiert werden konnte. Dadurch wurden die elektroche- mischen Analysenmethoden fUr die Praxis zunehmend interessanter. Die zahlreichen Publikationen iiber neue Verfahren in den letzten lahren sind damr ein Beweis.

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